Researchers at the
University of Massachusetts
believe they might have found an answer to the tire recycling problem:
a new twist on an old
vulcanization process that turns scrap tires into new rubber materials.
With mountains of used tires marring the landscape and creating environmental hazards,
methods to remove old tires from the waste stream have become an important component
in the battle to save the environment.
Drew Williams, a doctoral student in
polymer science and engineering at UMass, told NewsFactor that
recent studies indicate there are about two billion scrap tires
currently piled up in U.S. landfills. More than 273 million new
tires reaching the waste stream each year, 60 million of which end up in
landfills.
Mosquitoes, Rodents and Fire
"Scrap tires can fill with water and provide a breeding ground for
mosquitoes and rodents," Williams told NewsFactor. "They also present a
serious fire hazard, as large tire fires are difficult to extinguish and
spew toxins into the air as they burn."
While rubber is one the most useful materials of the modern age, it also
represents a particularly vexing recycling problems, said Richard
Farris, professor of polymer science in the engineering department at UMass.
"Rubber is difficult to recycle because it is chemically
cross-linked, and those links will not melt and will not dissolve,
unlike aluminum or glass," Farris told NewsFactor.
So, the current method for disposing of tires is that about 40 percent
are burned for fuel, 40 percent end up in landfills, and the rest of them are
chipped or ground into powder for use as industrial filler or to make synthetic
turfs for playing fields.
Heat and Pressure
As an alternative to the current methods, a team of researchers
led by Farris turned to a
process introduced way back in 1853 by Goodyear. The tire company
used a method in which the recycled rubber is
ground into a fine powder and mixed with unvulcanized rubber.
The mixture is then vulcanized, which, in essence, means that it is heated and
new cross-links are formed by adding sulfur or other chemicals to
restore its strength and elasticity.
Farris discovered that by subjecting the cross-linked powder to high
pressure (1,000 psi) and high and temperatures (200 degrees Celsius or 400
degrees Fahrenheit), the powder forms a solid rubber material.
"At high temperatures, the thermal energy breaks the chemical bonds and
re-forms them, creating a rubber material containing 100 percent
reclaimed rubber without significantly compromising the material's
quality," Farris said.
Typically, the new material retains 50 percent to 70 percent
of the original rubber's strength and elasticity, he added.
While the new material is not fit for use in making car tires,
Farris said, it could potentially be used for the soles and
heels of shoes, flooring materials and tires for lawn tractors.
Asphalt Extreme
Williams is involved in a related project to create a
rubber-asphalt composite using the same high temperature-high pressure
process as the rubber recycling project.
Unlike traditional asphalt that gets soft and tacky at high temperatures
and brittle at low temperatures, Williams said the new material remains stable and
flexible at both extremes.
"It could be used in shingles and possibly in paving surfaces if a
company could create a way to roll it out on a road," he suggested.
"With this process, we can reduce the amount of materials in our
landfills," Williams said, "and develop a starting material for new products -- and it's
cost-effective, because all we are doing is heating the scrap rubber and
subjecting it to high pressure."
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